4,4′-Bipyridine–butane-1,2,3,4-tetracarboxylic acid (1/1)
نویسندگان
چکیده
The title compound, C(10)H(8)N(2)·C(8)H(10)O(8), is an example of a system with a short O⋯H⋯N hydrogen bond [O⋯N = 2.565 (3) Å]. The crystal structure comprises a 1:1 adduct between 4,4'-bipyridine and butane-1,2,3,4-tetra-carboxylic acid, where both components are centrosymmetric. The component mol-ecules are linked through strong O⋯H⋯N hydrogen bonds, forming chains extending approximately along [11]. The chains are inter-connected by O⋯H⋯O hydrogen bonds and weak stacking inter-actions involving the pyridyl rings of the 4,4'-bipyridine mol-ecules [centroid-centroid distance = 3.73 (2) Å and inter-planar distance = 3.35 (1) Å]. The H atom of the short O⋯H⋯N hydrogen bond is disordered over two positions with site occupancy factors of ca 0.6 and 0.4. One methylene group is disordered over two positions; the site occupancy factors are ca 0.9 and 0.1.
منابع مشابه
Butane-1,2,3,4-tetracarboxylic acid–4,4′-bipyridine (1/2)
The hydro-thermal reaction of butane-1,2,3,4-tetra-carboxylic acid (H(4)butca), 4,4'-bipyridine (bipy) and Mn(SO(4))(2)·H(2)O afforded a new co-crystal, C(8)H(10)O(8)·2C(10)H(8)N(2) or H(4)butca·2(bipy), in which strong O-H⋯N hydrogen-bonding and weak π-π stacking [centroid-centroid distance = 3.8459 (19) Å] inter-actions assemble the organic mol-ecules into a three-dimensional supra-molecular ...
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The asymmetric unit of the title compound, C(8)H(10)O(8)·2H(2)O, contains one half-mol-ecule of butane-1,2,3,4-tetra-carboxylic acid and a water mol-ecule, with the complete tetra-acid generated by crystallographic inversion symmetry. Inter-molecular O-H⋯O hydrogen bonds form an extensive three-dimensional network, which consolidates the crystal packing.
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The title compound, C(14)H(6)O(7)·C(10)H(8)N(2), has been hydro-thermally synthesized. Structural ananlysis indicates that the crystals are produced by cocrystallization of naphthalene-1,4,5,8-tetra-carboxylic acid 1,8-anhydride and 4,4'-bipyridine (bpy) mol-ecules. The crystal packing is stabilized by inter-molecular O-H⋯N and C-H⋯O hydrogen bonds and π-π stacking inter-actions [centroid-centr...
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The asymmetric unit of the title compound, 2C(7)H(2)F(4)O(2)·C(10)H(8)N(2), contains one mol-ecule of 2,3,4,5-tetra-fluoro-benzoic acid (tfb) and half of a centrosymmetric 4,4'-bipyridine mol-ecule. Inter-molecular O-H⋯N hydrogen bonds link two tfb mol-ecules and one 4,4'-bipyridine mol-ecule into a trimer. Weak inter-molecular C-H⋯F inter-actions assemble these trimers into a three-dimensional...
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